论文标题
一种用于研究空间中复杂有机分子的表面化学途径的新型多光束设备
A new multi-beam apparatus for the study of surface chemistry routes to formation of complex organic molecules in space
论文作者
论文摘要
提出了多光束超高真空设备。在本文中,我们描述了一个新的实验室天体物理学实验的设计和构建 - VOTS de nouvellessynthèses(Venus) - 在乌云和情节环境中重现了复杂有机分子的固态非能形成条件。新的四个操作差异光束线的新型实现将用于确定各种反应的可行性和速率,这些反应有助于形成含有六个以上原子的分子。数据是通过傅立叶变换红外光谱和四极质质谱法收集的。涂有金色的样品持有人达到7至400 K之间的温度。仔细校准了设备,并开发了采集系统,以确保尽可能准确地记录实验参数。已经做出了巨大的努力,使光线线趋向于样品。已经开发了使用中性物种的反应系统(NH $ _3 $,H $ _2 $ CO)检查光束对齐的实验。对于NO+H系统获得了初步的原始结果,该结果表明化学仅发生在沉积物种的第一层外层,即化学层和物理层重合。鉴于James Webb太空望远镜即将推出,本文说明了新设备的特征,性能和未来潜力。我们表明,金星将通过其对表面科学和星体化学的贡献产生重大影响。
A multi-beam ultra-high vacuum apparatus is presented. In this article we describe the design and construction of a new laboratory astrophysics experiment -- VErs de NoUvelles Synthèses (VENUS) -- that recreates the solid-state non-energetic formation conditions of complex organic molecules in dark clouds and circumstellar environments. The novel implementation of four operational differentially-pumped beam lines will be used to determine the feasibility and the rates for the various reactions that contribute to formation of molecules containing more than six atoms. Data are collected by means of Fourier transform infrared spectroscopy and quadrupole mass spectrometry. The gold-coated sample holder reaches temperatures between 7 and 400 K. The apparatus was carefully calibrated and the acquisition system was developed to ensure that experimental parameters are recorded as accurately as possible. A great effort has been made to have the beam lines converge towards the sample. Experiments have been developed to check the beam alignment using reacting systems of neutral species (NH$_3$, H$_2$CO). Preliminary original results were obtained for the NO+H system, which shows that chemistry occurs only in the very first outer layer of the deposited species, that is the chemical layer and the physical layer coincide. This article illustrates the characteristics, performance, and future potential of the new apparatus in view of the forthcoming launch of the James Webb Space Telescope. We show that VENUS will have a major impact through its contributions to surface science and astrochemistry.