论文标题
Yttrium-cromium氧化物中的晶体和磁结构,磁化,热容量和各向异性磁曲效应
Crystalline and magnetic structures, magnetization, heat capacity and anisotropic magnetostriction effect in a yttrium-chromium oxide
论文作者
论文摘要
我们研究了几乎化学计量的y $ _ {0.97(2)} $ CR $ _ {0.98(2)} $ o $ $ $ $ _ {3.00(2)} $单晶,通过执行磁化,热容量和中子衍射的测量。尽管ycro $ _3 $复合行为像柔软的铁磁体,具有$ \ sim $ 0.05 t的柔软力量,但由于Cr $^{3+} $之间的强烈反铁磁性(AFM)相互作用,由于强烈的负corie curie -weiss curie -weiss -weiss weers cureiiss curie -weers weers and i。抗铁磁性可能表明倾斜的AFM结构。 AFM相过渡发生在$ t_ \ textrm {n} = $ 141.5(1)k,增加到$ t_ \ t_ \ textrm {n} $(5t)= 144.5(1)= 144.5(1)k at 5 t。 cr $^{3+} $沿晶体学\ emph {c}轴的旋转方向,带有空间group \ emph {pnma} $ t_ \ t_ \ textrm {n} $的正骨结构的轴。在12 K时,精制的力矩尺寸为2.45(6)$μ_\ textrm {b} $,$ \ sim $ 82 \%的理论饱和值3 $μ__\ textrm {b} $。 cr $^{3+} $旋转相互作用可能是二维iSing,就像倒数(1 1 0)散射平面一样。 Below $T_\textrm{N}$, the lattice configuration (\emph{a}, \emph{b}, \emph{c}, and \emph{V}) deviates largely downward from the Gr$\ddot{\textrm{u}}$neisen law, displaying an anisotropic magnetostriction effect and磁弹性效应。特别是,冷却时的样品收缩在AFM过渡温度以下增强。有证据表明,YCRO $ _3 $化合物的实际结晶对称性可能低于当前假设的化合物。此外,我们比较了$ t_ {2 \ textrm {g}} $ ycro $ _3 $和$ e_ \ textrm {g} $ la $ _ {7/8} $ _ {7/8} $ sr $ _ {1/8} $ mno $ _3 $ _3 $单晶$单晶可以进一步了解可能的对称性低点。
We have studied a nearly stoichiometric insulating Y$_{0.97(2)}$Cr$_{0.98(2)}$O$_{3.00(2)}$ single crystal by performing measurements of magnetization, heat capacity, and neutron diffraction. Albeit that the YCrO$_3$ compound behaviors like a soft ferromagnet with a coersive force of $\sim$ 0.05 T, there exist strong antiferromagnetic (AFM) interactions between Cr$^{3+}$ spins due to a strongly negative paramagnetic Curie-Weiss temperature, i.e., -433.2(6) K. The coexistence of ferromagnetism and antiferromagnetism may indicate a canted AFM structure. The AFM phase transition occurs at $T_\textrm{N} =$ 141.5(1) K, which increases to $T_\textrm{N}$(5T) = 144.5(1) K at 5 T. Within the accuracy of the present neuron-diffraction studies, we determine a G-type AFM structure with a propagation vector \textbf{k} = (1 1 0) and Cr$^{3+}$ spin directions along the crystallographic \emph{c} axis of the orthorhombic structure with space group \emph{Pnma} below $T_\textrm{N}$. At 12 K, the refined moment size is 2.45(6) $μ_\textrm{B}$, $\sim$ 82\% of the theoretical saturation value 3 $μ_\textrm{B}$. The Cr$^{3+}$ spin interactions are probably two-dimensional Ising like within the reciprocal (1 1 0) scattering plane. Below $T_\textrm{N}$, the lattice configuration (\emph{a}, \emph{b}, \emph{c}, and \emph{V}) deviates largely downward from the Gr$\ddot{\textrm{u}}$neisen law, displaying an anisotropic magnetostriction effect and a magnetoelastic effect. Especially, the sample contraction upon cooling is enhanced below the AFM transition temperature. There is evidence to suggest that the actual crystalline symmetry of YCrO$_3$ compound is probably lower than the currently assumed one. Additionally, we compared the $t_{2\textrm{g}}$ YCrO$_3$ and the $e_\textrm{g}$ La$_{7/8}$Sr$_{1/8}$MnO$_3$ single crystals for a further understanding of the reason for the possible symmetry lowering.