论文标题

Yttrium-cromium氧化物中的晶体和磁结构,磁化,热容量和各向异性磁曲效应

Crystalline and magnetic structures, magnetization, heat capacity and anisotropic magnetostriction effect in a yttrium-chromium oxide

论文作者

Zhu, Yinghao, Fu, Ying, Tu, Bao, Li, Tao, Miao, Jun, Zhao, Qian, Wu, Si, Xia, Junchao, Zhou, Pengfei, Huq, Ashfia, Schmidt, Wolfgang, Tang, Zikang, He, Zhubing, Li, Hai-Feng

论文摘要

我们研究了几乎化学计量的y $ _ {0.97(2)} $ CR $ _ {0.98(2)} $ o $ $ $ $ _ {3.00(2)} $单晶,通过执行磁化,热容量和中子衍射的测量。尽管ycro $ _3 $复合行为像柔软的铁磁体,具有$ \ sim $ 0.05 t的柔软力量,但由于Cr $^{3+} $之间的强烈反铁磁性(AFM)相互作用,由于强烈的负corie curie -weiss curie -weiss -weiss weers cureiiss curie -weers weers and i。抗铁磁性可能表明倾斜的AFM结构。 AFM相过渡发生在$ t_ \ textrm {n} = $ 141.5(1)k,增加到$ t_ \ t_ \ textrm {n} $(5t)= 144.5(1)= 144.5(1)k at 5 t。 cr $^{3+} $沿晶体学\ emph {c}轴的旋转方向,带有空间group \ emph {pnma} $ t_ \ t_ \ textrm {n} $的正骨结构的轴。在12 K时,精制的力矩尺寸为2.45(6)$μ_\ textrm {b} $,$ \ sim $ 82 \%的理论饱和值3 $μ__\ textrm {b} $。 cr $^{3+} $旋转相互作用可能是二维iSing,就像倒数(1 1 0)散射平面一样。 Below $T_\textrm{N}$, the lattice configuration (\emph{a}, \emph{b}, \emph{c}, and \emph{V}) deviates largely downward from the Gr$\ddot{\textrm{u}}$neisen law, displaying an anisotropic magnetostriction effect and磁弹性效应。特别是,冷却时的样品收缩在AFM过渡温度以下增强。有证据表明,YCRO $ _3 $化合物的实际结晶对称性可能低于当前假设的化合物。此外,我们比较了$ t_ {2 \ textrm {g}} $ ycro $ _3 $和$ e_ \ textrm {g} $ la $ _ {7/8} $ _ {7/8} $ sr $ _ {1/8} $ mno $ _3 $ _3 $单晶$单晶可以进一步了解可能的对称性低点。

We have studied a nearly stoichiometric insulating Y$_{0.97(2)}$Cr$_{0.98(2)}$O$_{3.00(2)}$ single crystal by performing measurements of magnetization, heat capacity, and neutron diffraction. Albeit that the YCrO$_3$ compound behaviors like a soft ferromagnet with a coersive force of $\sim$ 0.05 T, there exist strong antiferromagnetic (AFM) interactions between Cr$^{3+}$ spins due to a strongly negative paramagnetic Curie-Weiss temperature, i.e., -433.2(6) K. The coexistence of ferromagnetism and antiferromagnetism may indicate a canted AFM structure. The AFM phase transition occurs at $T_\textrm{N} =$ 141.5(1) K, which increases to $T_\textrm{N}$(5T) = 144.5(1) K at 5 T. Within the accuracy of the present neuron-diffraction studies, we determine a G-type AFM structure with a propagation vector \textbf{k} = (1 1 0) and Cr$^{3+}$ spin directions along the crystallographic \emph{c} axis of the orthorhombic structure with space group \emph{Pnma} below $T_\textrm{N}$. At 12 K, the refined moment size is 2.45(6) $μ_\textrm{B}$, $\sim$ 82\% of the theoretical saturation value 3 $μ_\textrm{B}$. The Cr$^{3+}$ spin interactions are probably two-dimensional Ising like within the reciprocal (1 1 0) scattering plane. Below $T_\textrm{N}$, the lattice configuration (\emph{a}, \emph{b}, \emph{c}, and \emph{V}) deviates largely downward from the Gr$\ddot{\textrm{u}}$neisen law, displaying an anisotropic magnetostriction effect and a magnetoelastic effect. Especially, the sample contraction upon cooling is enhanced below the AFM transition temperature. There is evidence to suggest that the actual crystalline symmetry of YCrO$_3$ compound is probably lower than the currently assumed one. Additionally, we compared the $t_{2\textrm{g}}$ YCrO$_3$ and the $e_\textrm{g}$ La$_{7/8}$Sr$_{1/8}$MnO$_3$ single crystals for a further understanding of the reason for the possible symmetry lowering.

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