论文标题
TATB在爆炸引起的休克条件下的结构研究
Structural study of TATB under detonation-induced shock conditions
论文作者
论文摘要
我们探索了不敏感的高爆炸性(IHE)1,3,5-三氨基-2,4,6-三硝基苯(TATB)在爆炸引起的冲击条件下,使用原位同步符X射线X射线衍射在100 ns使用常规或碰撞的引导驱动器中使用100 ns。在TATB的各种大小和形态的所有爆炸实验中,我们观察到TATB三斜晶体结构的稳定性。当爆炸前部通过TATB时,X射线衍射表明TATB的一部分表现出高达30+ GPA的压缩,随后进行了压力释放,并在几百纳米方面进行了持续分解。同样,对于TATB的单晶爆炸驱动的冲击压缩,三斜晶体结构的很大一部分似乎是稳定的,最高为60+ GPA。相反,在LLM-105 PBX的类似爆炸中,X射线衍射仅表示分解,而没有明显的压缩和TATB中看到的慢速分解。结果表明,在这些高压,温度和冲击条件下,TATB具有令人惊讶的弹性,为理解TATB的不敏感性提供了基准,这被认为是对高敏感性爆炸性不敏感的行业标准。结果还为TATB中的扩展反应区提供了有趣的信息,以及在这种独特的爆炸性中发起和传播爆炸的热点机制。
We explore the response of the insensitive high explosive (IHE) 1,3,5-Triamino-2,4,6- trinitrobenzene (TATB) under detonation-induced shock conditions using in-situ synchrotron X-ray diffraction in the 100 ns time scale using either a conventional or a colliding detonation drive. In all of the detonation experiments on various sizes and morphologies of TATB, we observe an extended stability of the TATB triclinic crystal structure. As the detonation front passes through the TATB, X-ray diffraction indicates a portion of the TATB exhibits a compression up to 30+ GPa, followed subsequently by a pressure release and continued decomposition over a few hundred nanoseconds. Likewise, for colliding detonation-driven shock compression of single crystals of TATB, a significant portion of the triclinic crystal structure appears to be stable up to 60+ GPa. Conversely, in similar detonations of a LLM-105 PBX, X-ray diffraction is simply indicative of decomposition without the apparent compression and slow decomposition seen in TATB. The results indicate the surprising resilience of TATB under these high-pressure, temperature and shock conditions, providing a baseline for understanding the insensitivity of TATB that is considered the industry standard for an insensitive high explosive. The results also provide intriguing information for the extended reaction zone in TATB, and the hot-spot mechanisms for initiating and propagating detonation in this uniquely insensitive explosive.