论文标题
非线性热响应的量子理论
Quantum Theory of Nonlinear Thermal Response
论文作者
论文摘要
在理论上还是在孔子上,热传输的线性行为已被广泛探索。另一方面,非线性热响应尚未完全讨论。鉴于热矢量电位理论[Phys。莱特牧师。 114,196601(2015)],我们开发了一种一般公式来计算线性和非线性动态热响应。在直流限制中,我们以线性订单响应恢复了众所周知的Mott关系和Wiedemann-Franz(WF)定律,将热电传导率η,导热率\ K {AppA}和电导率σ连接起来。具体而言,线性莫特的关系描述了线性η与σ相对于费米能的第一个衍生物成正比(因为我们称为第一个衍生物,其他衍生物是相似的);线性WF法律显示线性\ k {appa}与零导数成正比(即σ本身)。我们发现有高阶Mott关系和WF定律遵循订单依赖性关系。在第二阶的莫特关系表明二阶σ与第二阶η的零导数成正比。但是第二个WF定律表明,第二σ与\ k {appa}的第一个衍生物成正比。在第三阶,一次是折痕中的衍生命令。尽管我们仅明确计算了三阶响应,但我们可以推断出第n阶电导率与非线性Mott关系的N-2阶热电传导率的N-2-2-ther衍生物成正比;第n级电导率与非线性WF定律的n-1阶热导率的n-1-衍生物成正比。
The Linear behavior of thermal transport has been widely explored, both theoretically and ex?perimentally. On the other hand, the nonlinear thermal response has not been fully discussed. In light of the thermal vector potential theory [Phys. Rev. Lett. 114, 196601 (2015)], we develop a general formulation to calculate the linear and nonlinear dynamic thermal responses. In the DC limit, we recover the well-known Mott relation and the Wiedemann-Franz (WF) law at the linear order response, which link the thermoelectric conductivity η, thermal conductivity \k{appa} and electric conductivity σ together. To be specific, the linear Mott relation describes the linear η is proportional to the first derivative of σ with respect to Fermi energy (for brevity we call the first derivative, the others are similar); and the linear WF law shows the linear \k{appa} is proportional to the zero derivative (i.e. the σ itself). We found there are higher-order Mott relation and WF law which follow an order-dependent relation. At the second order, the Mott relation indicates that the second order σ is proportional to the zero derivative of the second order η; but the second WF law shows that the second σ is proportional to the first derivative of \k{appa}. At the third order, the derivative order in?creases once. Although we only did explicit calculate up to the third order response, we can deduce that the n-th order electric conductivity is proportional to the n-2-th derivative of the n-th order thermoelectric conductivity for the nonlinear Mott relation; and the n-th order electric conductivity is proportional to the n-1-th derivative of the n-th order thermal conductivity for the nonlinear WF law.