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Smart city architecture brings all the underlying architectures, i.e., Internet of Things (IoT), Cyber-Physical Systems (CPSs), Internet of Cyber-Physical Things (IoCPT), and Internet of Everything (IoE), together to work as a system under its umbrella. The goal of smart city architecture is to come up with a solution that may integrate all the real-time response applications. However, the cyber-physical space poses threats that can jeopardize the working of a smart city where all the data belonging to people, systems, and processes will be at risk. Various architectures based on centralized and distributed mechanisms support smart cities; however, the security concerns regarding traceability, scalability, security services, platform assistance, and resource management persist. In this paper, private blockchain-based architecture Decentralized Smart City of Things (DSCoT) is proposed. It actively utilizes fog computing for all the users and smart devices connected to a fog node in a particular management system in a smart city, i.e., a smart house or hospital, etc. Non-fungible tokens (NFTs) have been utilized for representation to define smart device attributes. NFTs in the proposed DSCoT architecture provide devices and user authentication (IoT) functionality. DSCoT has been designed to provide a smart city solution that ensures robust security features such as Confidentiality, Integrity, Availability (CIA), and authorization by defining new attributes and functions for Owner, User, Fog, and IoT devices authentication. The evaluation of the proposed functions and components in terms of Gas consumption and time complexity has shown promising results. Comparatively, the Gas consumption for minting DSCoT NFT showed approximately 27%, and a DSCoT approve() was approximately 11% more efficient than the PUF-based NFT solution.