论文标题
非临界纳米颗粒冰箱:设计原理和约束
Nonreciprocal nanoparticle refrigerators: design principles and constraints
论文作者
论文摘要
我们通过将分子动力学模拟与随机热力学相结合,研究了在不同温度下通过非偏置力相互作用的两个纳米颗粒之间的热传递。我们的模拟表明,可以构建纳米冰箱,从而以非雷神力量施加的力量来产生从冷到热储层的净传热。将从随机热力学的概念应用到最小抑制的Langevin模型时,我们得出了工作,热量和效率波动的精确分析表达预测,这些预测再现从分子动力学模拟中提取的热力学数量。该理论仅涉及一个未知参数,即有效的摩擦系数,我们估计将分子动力学模拟的结果拟合到理论预测。使用此框架,我们还建立了设计原理,以确定在我们的纳米冰箱的功率波动中达到一定程度不确定性所需的最小熵产生。综上所述,我们的结果阐明了如何通过使用非互惠力准确地量化和控制自然和人造纳米机中热流的方向和波动。
We study the heat transfer between two nanoparticles held at different temperatures that interact through nonreciprocal forces, by combining molecular dynamics simulations with stochastic thermodynamics. Our simulations reveal that it is possible to construct nano refrigerators that generate a net heat transfer from a cold to a hot reservoir at the expense of power exerted by the nonreciprocal forces. Applying concepts from stochastic thermodynamics to a minimal under-damped Langevin model, we derive exact analytical expressions predictions for the fluctuations of work, heat, and efficiency, which reproduce thermodynamic quantities extracted from the molecular dynamics simulations. The theory only involves a single unknown parameter, namely an effective friction coefficient, which we estimate fitting the results of the molecular dynamics simulation to our theoretical predictions. Using this framework, we also establish design principles which identify the minimal amount of entropy production that is needed to achieve a certain amount of uncertainty in the power fluctuations of our nano refrigerator. Taken together, our results shed light on how the direction and fluctuations of heat flows in natural and artificial nano machines can be accurately quantified and controlled by using nonreciprocal forces.